Journal article
Amide functionalised dithiocarbamate ruthenium(II) bis-bipyridyl receptors: A new class of redox-responsive anion sensor
- Abstract:
-
The synthesis of new amide functionalised ruthenium(II) bis-bipyridyl dithiocarbamate receptor molecules is described. These hosts have been shown to sense the binding of anions electrochemically. Proton NMR titration studies in dmso-d6:MeCN-d3 (1:1) solvent mixtures indicate that the receptors selectively bind dihydrogen phosphate. A single crystal X-ray structure of one receptor reveals the crucial role of amide-anion hydrogen bonding interactions in the binding of sulphate. Cyclic and squa...
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- Publication status:
- Published
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Bibliographic Details
- Journal:
- INORGANICA CHIMICA ACTA
- Volume:
- 361
- Issue:
- 6
- Pages:
- 1689-1698
- Publication date:
- 2008-05-05
- DOI:
- ISSN:
-
0020-1693
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:40731
- UUID:
-
uuid:3c046acf-2fec-4746-b8ab-60cb5d55db36
- Local pid:
- pubs:40731
- Source identifiers:
-
40731
- Deposit date:
- 2012-12-19
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- Copyright date:
- 2008
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