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Amide functionalised dithiocarbamate ruthenium(II) bis-bipyridyl receptors: A new class of redox-responsive anion sensor

Abstract:

The synthesis of new amide functionalised ruthenium(II) bis-bipyridyl dithiocarbamate receptor molecules is described. These hosts have been shown to sense the binding of anions electrochemically. Proton NMR titration studies in dmso-d6:MeCN-d3 (1:1) solvent mixtures indicate that the receptors selectively bind dihydrogen phosphate. A single crystal X-ray structure of one receptor reveals the crucial role of amide-anion hydrogen bonding interactions in the binding of sulphate. Cyclic and squa...

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Publication status:
Published

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Publisher copy:
10.1016/j.ica.2007.02.030

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
INORGANICA CHIMICA ACTA
Volume:
361
Issue:
6
Pages:
1689-1698
Publication date:
2008-05-05
DOI:
ISSN:
0020-1693
Language:
English
Keywords:
Pubs id:
pubs:40731
UUID:
uuid:3c046acf-2fec-4746-b8ab-60cb5d55db36
Local pid:
pubs:40731
Source identifiers:
40731
Deposit date:
2012-12-19

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