Journal article
Catalyst‐Free Selective Reduction of Nitrogen Dioxide to Nitric Oxide
- Abstract:
- Nitrogen dioxide (NO2) is a highly toxic gas and a notorious respiratory irritant that contributes to the greenhouse effect and acid rain. Herein, we study the catalyst‐free reduction of NO2 with boranes, silanes, and the hydrogen surrogates 1,4‐cyclohexadiene and isopropyl alcohol, resulting in the selective formation of nitric oxide (NO). Selective NO generation was confirmed by electron paramagnetic resonance spectroscopy and low‐temperature 15N{1H} nuclear magnetic resonance spectroscopy. Additionally, density functional theory calculations have been employed to probe the mechanism of these reductions.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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(Preview, Version of record, pdf, 1.3MB, Terms of use)
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- Publisher copy:
- 10.1002/chem.71267
Authors
- Publisher:
- Wiley
- Journal:
- Chemistry - A European Journal More from this journal
- Article number:
- e71267
- Publication date:
- 2026-06-18
- Acceptance date:
- 2026-06-02
- DOI:
- EISSN:
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1521-3765
- ISSN:
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0947-6539
- Language:
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English
- Keywords:
- Source identifiers:
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4246605
- Deposit date:
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2026-06-19
- ARK identifier:
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Terms of use
- Copyright date:
- 2026
- Licence:
- CC Attribution (CC BY)
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