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Incipient carbonate melting drives metal and sulfur mobilization in the mantle

Abstract:
We present results from high-pressure, high-temperature experiments that generate incipient carbonate melts at mantle conditions (~90 kilometers depth and temperatures between 750° and 1050°C). We show that these primitive carbonate melts can sequester sulfur in its oxidized form of sulfate, as well as base and precious metals from mantle lithologies of peridotite and pyroxenite. It is proposed that these carbonate sulfur–rich melts may be more widespread than previously thought and that they may play a first-order role in the metallogenic enhancement of localized lithospheric domains. They act as effective agents to dissolve, redistribute, and concentrate metals within discrete domains of the mantle and into shallower regions within Earth, where dynamic physicochemical processes can lead to ore genesis at various crustal depths.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1126/sciadv.adk5979

Authors

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Role:
Author
ORCID:
0000-0002-5626-561X
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Role:
Author
ORCID:
0000-0001-6873-7816
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Institution:
University of Oxford
Division:
MPLS
Department:
Earth Sciences
Role:
Author
ORCID:
0000-0002-7569-6909


Publisher:
American Association for the Advancement of Science
Journal:
Science Advances More from this journal
Volume:
10
Issue:
12
Article number:
eadk5979
Publication date:
2024-03-22
Acceptance date:
2024-02-20
DOI:
EISSN:
2375-2548
Pmid:
38517954


Language:
English
Pubs id:
1941754
Local pid:
pubs:1941754
Deposit date:
2024-04-03
ARK identifier:

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