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Hybrid perovskites, metal–organic frameworks, and beyond: unconventional degrees of freedom in molecular frameworks

Abstract:

The structural degrees of freedom of a solid material are the various distortions most straightforwardly activated by external stimuli such as temperature, pressure, or adsorption. One of the most successful design strategies in materials chemistry involves controlling these individual distortions to produce useful collective functional responses. In a ferroelectric such as lead titanate, for example, the key degree of freedom involves asymmetric displacements of Pb2+ and Ti4+ cations; it ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.accounts.0c00797

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Publisher:
American Chemical Society Publisher's website
Journal:
Accounts of Chemical Research Journal website
Volume:
54
Issue:
5
Pages:
1288–1297
Publication date:
2021-02-18
Acceptance date:
2021-02-08
DOI:
EISSN:
2052-4129
ISSN:
2052-4110
Language:
English
Keywords:
Pubs id:
1160358
Local pid:
pubs:1160358
Deposit date:
2021-02-09

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