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Self-assembly in the electrical double layer of ionic liquids.

Abstract:
We have studied the structure of two ionic liquids confined between negatively charged mica sheets. Both liquids exhibit interfacial layering, however the repeat distance is dramatically different for the two liquids. Our results suggest a transition from alternating cation-anion monolayers to tail-to-tail cation bilayers when the length of the cation hydrocarbon chain is increased.
Publication status:
Published

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Publisher copy:
10.1039/c1cc11322d

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
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Journal:
Chemical communications (Cambridge, England)
Volume:
47
Issue:
23
Pages:
6572-6574
Publication date:
2011-06-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:387a2a14-3d00-495b-a0d7-e0715e43ef46
Source identifiers:
353674
Local pid:
pubs:353674
Language:
English

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