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An approximate theoretical treatment of ion transfer processes at asymmetric microscopic and nanoscopic liquid-liquid interfaces: Single and double potential pulse techniques

Abstract:

Simple theory for the electrochemical study of reversible ion transfer processes at micro- and nano-liquid|liquid interfaces supported on a capillary is presented. Closed-form expressions are obtained for the response in normal pulse and differential double pulse voltammetries, which describe adequately the particular behaviour of these systems due to the 'asymmetric' ion diffusion inside and outside the capillary. The use of different potential pulse techniques for the determination of the f...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
CHEMICAL PHYSICS LETTERS
Volume:
597
Pages:
126-133
Publication date:
2014-03-28
DOI:
ISSN:
0009-2614
UUID:
uuid:3756ba8a-a200-4910-b685-f040e5e8d3c3
Local pid:
pubs:459751
Source identifiers:
459751
Deposit date:
2014-06-17

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