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Controlling intermolecular spin interactions of La@C82 in empty fullerene matrices

Abstract:

The ESR properties and crystal structures of solid-state La@C82 in empty fullerene matrices were investigated by changing the concentration of La@C82 and the species of an empty fullerene matrix: C60, C70, C78(C2v(3)), C82(C2) and C84(D2d(4)). The rotational correlation time of La@C82 molecules tended to be shorter when La@C82 is dispersed in larger fullerene matrices because large C2n molecules provide more space for La@C82 molecules for rotating. La@C 82 dispersed in a hcp-C82 matrix showed...

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Publisher copy:
10.1039/b913593f

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Journal:
Physical Chemistry Chemical Physics
Volume:
12
Issue:
7
Pages:
1618-1623
Publication date:
2010-01-01
DOI:
ISSN:
1463-9076
Language:
English
Pubs id:
pubs:161455
UUID:
uuid:37029754-f82d-4e24-b470-30ced7213485
Local pid:
pubs:161455
Source identifiers:
161455
Deposit date:
2012-12-20

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