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HPCO - A phosphorus-containing analogue of isocyanic acid

Abstract:
We describe the isolation and spectroscopic characterization of the heavier phosphorus‐containing analogue of isocyanic acid (HPCO), and its isotopologue (DPCO). This fundamental small molecule, which has been postulated to exist in interstellar space, has thus far only been observed at low gas phase concentrations or in inert gas matrices. In this report we describe its synthesis, spectroscopic properties, and reactivity in solution.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/ange.201700368

Authors

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Role:
Author
ORCID:
0000-0002-7831-1410
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Role:
Author
ORCID:
0000-0001-9060-7065
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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Lady Margaret Hall
Role:
Author
ORCID:
0000-0002-7311-1663


Publisher:
Wiley
Journal:
Angewandte Chemie More from this journal
Volume:
129
Issue:
14
Pages:
3969-3973
Publication date:
2017-03-02
Acceptance date:
2017-02-13
DOI:
EISSN:
1521-3757
ISSN:
0044-8249


Keywords:
Pubs id:
pubs:832445
UUID:
uuid:349aa256-9e73-47ef-9692-7dcd80150e5c
Local pid:
pubs:832445
Source identifiers:
832445
Deposit date:
2018-08-30
ARK identifier:

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