Journal article
Comparative study of microscopic charge dynamics in crystalline acceptor-substituted oligothiophenes.
- Abstract:
-
By performing microscopic charge transport simulations for a set of crystalline dicyanovinyl-substituted oligothiophenes, we find that the internal acceptor-donor-acceptor molecular architecture combined with thermal fluctuations of dihedral angles results in large variations of local electric fields, substantial energetic disorder, and pronounced Poole-Frenkel behavior, which is unexpected for crystalline compounds. We show that the presence of static molecular dipoles causes large energetic...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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Authors
Funding
Bundesministerium für Bildung und Forschung
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Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 134
- Issue:
- 13
- Pages:
- 6052-6056
- Publication date:
- 2012-04-01
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- Source identifiers:
-
403009
Item Description
- Language:
- English
- Pubs id:
-
pubs:403009
- UUID:
-
uuid:32851eda-9711-450f-8d9f-4c7a513f6138
- Local pid:
- pubs:403009
- Deposit date:
- 2013-09-26
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2012
- Notes:
- © 2012 American Chemical Society. The full text of this article is not available in ORA. You may be able to access the article via the publisher copy link above.
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