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Coupled-channel statistical theory of the N(D-2)+H-2 and O(D-1)+H-2 insertion reactions

Abstract:
A detailed statistical theory of atom-diatom insertion reactions is derived by combining the early statistical ideas of Pechukas and Light with the coupled-channel capture theory of Clary and Henshaw. The theory is applied to the N(2D)+H2 and O(1D)+H2 reactions and found to give results in good agreement with the exact quantum mechanical integral cross sections reported recently by Honvault and Launay. © 2001 Elsevier Science B.V.
Publication status:
Published

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Authors


Rackham, EJ More by this author
Huarte-Larranaga, F More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Journal:
CHEMICAL PHYSICS LETTERS
Volume:
343
Issue:
3-4
Pages:
356-364
Publication date:
2001-08-03
DOI:
ISSN:
0009-2614
URN:
uuid:31b02015-692a-468c-8aa2-d4eae1beda4a
Source identifiers:
37926
Local pid:
pubs:37926
Language:
English

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