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Metal-halide Nanoparticle Formation: Electrolytic and Chemical Synthesis of Mercury(I) Chloride Nanoparticles

Abstract:

Mercury(I) chloride (Hg2Cl2) nanoparticles (NPs) are synthesised for the first time by using two different techniques. First, particles are formed by implosion of a calomel nanolayer, induced by partial electrolysis at a mercury hemisphere microelectrode. The resulting NPs are then characterised by the nanoimpact method, demonstrating the first time metal chloride NPs have been sized by this technique and showing the ability to form and study NPs insitu. Second, Hg2...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1002/celc.201402401

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Materials
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
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Funding agency for:
Bartlett, TR
More from this funder
Funding agency for:
Batchelor-McAuley, C
Publisher:
Wiley-VCH Publisher's website
Journal:
ChemElectroChem Journal website
Volume:
2
Issue:
4
Pages:
522-528
Publication date:
2015-04-05
DOI:
EISSN:
2196-0216
ISSN:
2196-0216
URN:
uuid:3168b576-b53a-4b3f-a041-1b9a949f68ea
Source identifiers:
523501
Local pid:
pubs:523501

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