P-type conductivity in Sn-doped Sb₂Se₃

Journal article

Antimony selenide (Sb2Se3) is a promising absorber material for thin-film photovoltaics. However, certain areas of fundamental understanding of this material remain incomplete and this presents a barrier to further efficiency gains. In particular, recent studies have highlighted the role of majority carrier type and extrinsic doping in drastically changing the performance of high efficiency devices [1]. Herein, Sndoped Sb2Se3 bulk crystals are shown to exhibit p-type conductivity using Hall effect and hot-probe measurements. The measured conductivities are higher than those achieved through native defects alone, but with a carrier density (up to 7.4 × 1014 cm−3) several orders of magnitude smaller than the quantity of Sn included in the source material. Additionally, a combination of ultraviolet, X-ray and hard X-ray photoemission spectroscopies are employed to obtain a non-destructive depth profile of the valence band maximum, confirming p-type conductivity and indicating a majority carrier type inversion layer at the surface. Finally, these results are supported by density functional theory calculations of the defect formation energies in Sn-doped Sb2Se3, showing a possible limit on the carrier concentration achievable with Sn as a dopant. This study sheds light on the effectiveness of Sn as a p-type dopant in Sb2Se3 and highlights avenues for further optimisation of doped Sb2Se3 for solar energy devices

Authors: Hobson, TDC; Shiel, H; Savory, CN; Swallow, JEN; Jones, LAH

• Publication status: Published
• Peer review status: Peer reviewed
• Publisher: IOP Publishing
• Journal: JPhys Energy
• Volume: 4
• Issue: 4
• Pages: 045006-045006
• Publication date: 2022-09-13
• DOI: 10.1088/2515-7655/ac91a6
• EISSN: 2515-7655
• ISSN: 2515-7655
• Language: English
• Keywords: Metallurgy; Materials science; Antimony; Selenide; Photovoltaic system; Condensed matter physics; Dopant; Photovoltaics; Doping; Charge-carrier density; Analytical Chemistry (journal); Optoelectronics; Conductivity; Chemistry; Physical chemistry