- Abstract:
- The synthesis of a phosphorus(III) compound bearing a N,N-bis(3,5-di-tert-butyl-2-phenoxy)amide ligand is reported. This species has been found to react with ammonia and water, activating the E-H bonds in both substrates by formal oxidative addition to afford the corresponding phosphorus(V) compounds. In the case of water, both O-H bonds can be activated, splitting the molecule into its constituent elements. To our knowledge, this is the first example of a compound based on main group elements that sequentially activates water in this manner.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's version
- Files:
-
-
(pdf, 789.6KB)
-
- Publisher copy:
- 10.1002/anie.201506998
-
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- Publisher:
- Wiley Publisher's website
- Journal:
- Angewandte Chemie International Edition Journal website
- Volume:
- 54
- Issue:
- 46
- Pages:
- 13758-13763
- Publication date:
- 2015-09-25
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- URN:
-
uuid:301afa49-62f1-4f9d-94e9-9f28e0dbd2dd
- Source identifiers:
-
575141
- Local pid:
- pubs:575141
- Language:
- English
- Keywords:
- Copyright holder:
- Robinson et al.
- Copyright date:
- 2015
- Notes:
- © 2015 The Authors. Published by Wiley-VCH Verlag GmbH and Co. KGaA for Gesellschaft Deutscher Chemiker (GDCh). This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
Journal article
E-H bond activation of ammonia and water by a geometrically constrained phosphorus(III) compound
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