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HPCO-A phosphorus-containing analogue of isocyanic acid.

Abstract:
We describe the isolation and spectroscopic characterization of the heavier phosphorus-containing analogue of isocyanic acid (HPCO), and its isotopologue (DPCO). This fundamental small molecule, which has been postulated to exist in interstellar space, has thus far only been observed at low gas phase concentrations or in inert gas matrices. In this report we describe its synthesis, spectroscopic properties, and reactivity in solution.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/anie.201700368

Authors


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Institution:
University of Oxford
Oxford college:
Lady Margaret Hall
Role:
Author


Publisher:
Wiley
Journal:
Angewandte Chemie Internationa Edition More from this journal
Volume:
56
Issue:
14
Pages:
3911-3915
Publication date:
2017-03-02
Acceptance date:
2017-02-13
DOI:
EISSN:
1521-3773
ISSN:
1433-7851


Language:
English
Keywords:
Pubs id:
pubs:685288
UUID:
uuid:2fe23cfc-199c-4a0d-b2dc-7e4e6929c9dd
Local pid:
pubs:685288
Source identifiers:
685288
Deposit date:
2017-05-05

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