- Abstract:
-
The high-spin (S = 1) tetrahedral Ni(II) complex [Ni{(i)Pr2P(Se)NP(Se)(i)Pr2}2] was investigated by magnetometry, spectroscopic, and quantum chemical methods. Angle-resolved magnetometry studies revealed the orientation of the magnetization principal axes. The very large zero-field splitting (zfs), D = 45.40(2) cm(-1), E = 1.91(2) cm(-1), of the complex was accurately determined by far-infrared magnetic spectroscopy, directly observing transitions between the spin sublevels of the triplet gro...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Publisher copy:
- 10.1021/jacs.5b06716
-
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- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 137
- Issue:
- 40
- Pages:
- 12923-12928
- Publication date:
- 2015-10-05
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- URN:
-
uuid:2f04f370-f10e-4ff2-9a4b-6ab9274545f6
- Source identifiers:
-
572531
- Local pid:
- pubs:572531
- Language:
- English
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2015
- Notes:
- Copyright © 2015 American Chemical Society.
Journal article
Direct observation of very large zero-field splitting in a tetrahedral Ni(II)Se4 coordination complex
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Max Planck Society
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