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Direct observation of very large zero-field splitting in a tetrahedral Ni(II)Se4 coordination complex

Abstract:

The high-spin (S = 1) tetrahedral Ni(II) complex [Ni{(i)Pr2P(Se)NP(Se)(i)Pr2}2] was investigated by magnetometry, spectroscopic, and quantum chemical methods. Angle-resolved magnetometry studies revealed the orientation of the magnetization principal axes. The very large zero-field splitting (zfs), D = 45.40(2) cm(-1), E = 1.91(2) cm(-1), of the complex was accurately determined by far-infrared magnetic spectroscopy, directly observing transitions between the spin sublevels of the triplet gro...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/jacs.5b06716

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Grant:
Special Research Account
Max Planck Society More from this funder
Alexander von Humboldt Foundation More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
137
Issue:
40
Pages:
12923-12928
Publication date:
2015-10-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:2f04f370-f10e-4ff2-9a4b-6ab9274545f6
Source identifiers:
572531
Local pid:
pubs:572531
Language:
English

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