- Abstract:
- Pentaborane(9) reacts with [Fe(PMe3)3(η 2-CH2PMe2)H] to give [2,3-{Fe(PMe 3)2}2(μ-H)B4H9] (1) and [2-{Fe(PMe3)3}B4H8] (2) in yields of up to 1 and 22% respectively; the X-ray crystal structure of (1) shows a nido-pentaborane(9) structure in which a BH3 fragment caps the Fe2B face.
- Publication status:
- Published
- Publisher copy:
- 10.1039/c39900001234
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
- Issue:
- 18
- Pages:
- 1234-1236
- Publication date:
- 1990-09-15
- DOI:
- ISSN:
-
0022-4936
- URN:
-
uuid:2ed08cd3-8d4b-4851-a6d9-c114c9015a9a
- Source identifiers:
-
51387
- Local pid:
- pubs:51387
- Language:
- English
- Copyright date:
- 1990
Journal article
SYNTHESIS OF SMALL NIDO-FERRAPENTABORANES - A NOVEL BORANE-CAPPED NIDO-DIFERRAPENTABORANE
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