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SYNTHESIS OF SMALL NIDO-FERRAPENTABORANES - A NOVEL BORANE-CAPPED NIDO-DIFERRAPENTABORANE

Abstract:
Pentaborane(9) reacts with [Fe(PMe3)3(η 2-CH2PMe2)H] to give [2,3-{Fe(PMe 3)2}2(μ-H)B4H9] (1) and [2-{Fe(PMe3)3}B4H8] (2) in yields of up to 1 and 22% respectively; the X-ray crystal structure of (1) shows a nido-pentaborane(9) structure in which a BH3 fragment caps the Fe2B face.
Publication status:
Published

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Publisher copy:
10.1039/c39900001234

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS
Issue:
18
Pages:
1234-1236
Publication date:
1990-09-15
DOI:
ISSN:
0022-4936
URN:
uuid:2ed08cd3-8d4b-4851-a6d9-c114c9015a9a
Source identifiers:
51387
Local pid:
pubs:51387
Language:
English

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