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Lithiation-electrophilic substitution of N-thiopivaloylazetidine.

Abstract:
The fourth protocol: the rarely studied N-thiopivaloyl group plays a crucial role in mediating efficient α lithiation and incorporation of diverse electrophiles onto an azetidine ring; in the presence of chiral ligands, this chemistry also provides the first example of an enantioselective electrophilic substitution on a four-membered ring.
Publication status:
Published

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Publisher copy:
10.1002/anie.201000058

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Angewandte Chemie (International ed. in English)
Volume:
49
Issue:
16
Pages:
2900-2903
Publication date:
2010-04-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Source identifiers:
51917
Language:
English
Keywords:
Pubs id:
pubs:51917
UUID:
uuid:2cc7b82f-084c-45f0-bab8-bd63f56bbd74
Local pid:
pubs:51917
Deposit date:
2012-12-19

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