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REMPI-TOF studies of the translational anisotropy and the polarization of the O ((1)D2) photofragment angular momentum following ozone photolysis at 298 nm.

Abstract:

The translational anisotropy and the polarization of the electronic angular momentum of the O ((1)D2) fragment produced from the 298 nm photodissociation of ozone have been determined using resonance enhanced multiphoton ionization (REMPI) in conjunction with time-of-flight mass spectrometry (TOFMS). The translational anisotropy parameter beta, which is necessarily averaged over the O2 co-fragment rotational distribution, is measured to be 1.08 +/- 0.04. This is consistent with that expected ...

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Publication status:
Published

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Publisher copy:
10.1039/b517523b

Authors


Horrocks, SJ More by this author
Pearson, PJ More by this author
Ritchie, GA More by this author
Journal:
Physical chemistry chemical physics : PCCP
Volume:
8
Issue:
16
Pages:
1954-1962
Publication date:
2006-04-05
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
URN:
uuid:2cc6c15b-010c-48d4-a077-a6c14b968359
Source identifiers:
39931
Local pid:
pubs:39931

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