- Abstract:
- This work introduces a simple, single-step, impedance-derived capacitance spectroscopic approach as a convenient and direct way of reporting the heterogeneous rate of electron-transfer between an electrode and solution-phase redox species. The proposed methodology requires no equivalent circuit analysis or data fitting and is equally applicable to the strong coupling (diffusion-mediated) or weak coupling electron-transfer regimes.
- Publication status:
- Published
- Publisher copy:
- 10.1021/ac402378n
-
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- Journal:
- Analytical chemistry
- Volume:
- 85
- Issue:
- 22
- Pages:
- 10920-10926
- Publication date:
- 2013-11-05
- DOI:
- EISSN:
-
1520-6882
- ISSN:
-
0003-2700
- URN:
-
uuid:2c51e070-7bb8-4b08-a98b-28e5341e0960
- Source identifiers:
-
443399
- Local pid:
- pubs:443399
- Language:
- English
- Copyright date:
- 2013
Journal article
A facile measurement of heterogeneous electron transfer kinetics.
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