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Stille coupling made easier-the synergic effect of copper(I) salts and the fluoride ion.

Abstract:
CsF and Cul do the trick: Stille coupling reactions of aryl/vinyl iodides, triflates, and bromides with aryl/vinyl stannanes are greatly enhanced by the inclusion of CsF and Cul in the reaction mixture (see scheme; Conditions A: [Pd(PPh 3) 4]/CsF/ Cul/DW/45 °C; Conditions B: PdCl 2/ PtBu 3/CsF/Cul/DMF/45 °C).
Publication status:
Published

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Publisher copy:
10.1002/anie.200352979

Authors

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author


Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
43
Issue:
9
Pages:
1132-1136
Publication date:
2004-02-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851


Language:
English
Keywords:
Pubs id:
pubs:118251
UUID:
uuid:2c145de4-118b-4571-b49a-8621e1e6e220
Local pid:
pubs:118251
Source identifiers:
118251
Deposit date:
2013-11-16
ARK identifier:

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