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Guiding principles of hydrogenase catalysis instigated and clarified by protein film electrochemistry

Abstract:

Protein film electrochemistry (PFE) is providing cutting-edge insight into the chemical principles underpinning biological hydrogen. Attached to an electrode, many enzymes exhibit "reversible" electrocatalytic behavior, meaning that a catalyzed redox reaction appears reversible or quasi-reversible when viewed by cyclic voltammetry. This efficiency is most relevant for enzymes that are inspiring advances in renewable energy, such as hydrogen-activating and CO2-reducing enzymes. Exploiting the ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.accounts.6b00027

Authors

More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0002-9549-4220
More by this author
Role:
Author
ORCID:
0000-0002-5291-4328


Publisher:
American Chemical Society
Journal:
Accounts of Chemical Research More from this journal
Volume:
49
Issue:
5
Pages:
884-892
Publication date:
2016-04-22
Acceptance date:
2016-04-08
DOI:
EISSN:
1520-4898
ISSN:
0001-4842
Pmid:
27104487


Language:
English
Keywords:
Pubs id:
pubs:619888
UUID:
uuid:2b761b1a-aff5-4c2f-93d2-f5702373da60
Local pid:
pubs:619888
Source identifiers:
619888
Deposit date:
2018-08-30
ARK identifier:

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