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Fully quantum state-resolved inelastic scattering of NO(X) + Kr: differential cross sections and product rotational alignment.

Abstract:
Fully quantum state selected and resolved inelastic scattering of NO(X) by krypton has been investigated. Initial Λ-doublet state selection is achieved using an inhomogeneous hexapole electric field. Differential cross sections and even-moment polarization dependent differential cross sections have been obtained at a collision energy of 514 cm^−1 for both spin-orbit and parity conserving and changing collisions. Experimental results are compared with those obtained from quantum scattering calculations and are shown to be in very good agreement. Hard shell quantum scattering calculations are also performed to determine the effects of the different parts of the potential on the scattering dynamics. Comparisons are also made with the NO(X)+Ar system.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1063/1.4897558

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author


Publisher:
American Institute of Physics
Journal:
Journal of Chemical Physics More from this journal
Volume:
141
Issue:
16
Pages:
164306
Publication date:
2014-10-24
Acceptance date:
2014-09-01
DOI:
EISSN:
1089-7690
ISSN:
0021-9606


Language:
English
Pubs id:
pubs:488495
UUID:
uuid:2b4af51f-c8e7-415b-bed4-5fdcaab60338
Local pid:
pubs:488495
Source identifiers:
488495
Deposit date:
2014-11-08

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