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Complexes of iron(II) with silylated pentalene ligands; building blocks for homo- and heterobimetallics

Abstract:

A range of iron(II) complexes incorporating the silylated pentalene ligands (Pn † H = 1,4-{Si i Pr 3 } 2 C 8 H 5 and Pn †  = 1,4-{Si i Pr 3 } 2 C 8 H 4 ) have been investigated as model molecules/building blocks for metallocene-based polymers. Six complexes have been synthesised and extensively characterised by a range of techniques, including by cyclic voltammetry and X-ray diffraction studies. Amongst these compounds are the homobimetallic [Cp ∗ Fe] 2 (μ-Pn † ) which is a fused analogue of ...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1016/j.poly.2016.03.001

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Johnston, DR More by this author
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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
St Hughs College
Tsoureas, N More by this author
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Grant:
EP/M023885/1
University of Sussex More from this funder
Publisher:
Elsevier Publisher's website
Journal:
Polyhedron Journal website
Volume:
116
Issue:
1
Pages:
26-37
Publication date:
2016-03-05
DOI:
EISSN:
1873-3719
ISSN:
0277-5387
Pubs id:
pubs:612269
URN:
uri:2b032bd9-10ce-4c0b-a2b4-d67a4635c585
UUID:
uuid:2b032bd9-10ce-4c0b-a2b4-d67a4635c585
Local pid:
pubs:612269

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