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Sr(3)Co(2)O(4.33)h(0.84): an extended transition metal oxide-hydride.

Abstract:

Reaction of the n = 2 Ruddlesden-Popper oxide Sr(3)Co(2)O(5.80) with CaH(2) yields an extended oxide-hydride phase: Sr(3)Co(2)O(4.33)H(0.84). Neutron powder diffraction data reveal the material adopts a body-centered orthorhombic structure (Immm: a = 3.7551(5) Å, b = 3.7048(4) Å, c = 21.480(3) Å) in which the hydride ions are accommodated within disordered CoO(1.16)H(0.46) layers. Low temperature neutron powder diffraction data show no evidence for long-range magnetic order, suggesting the ch...

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Publication status:
Published

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Publisher copy:
10.1021/ic101613b

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry More from this journal
Volume:
49
Issue:
23
Pages:
11062-11068
Publication date:
2010-12-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Language:
English
Pubs id:
pubs:93169
UUID:
uuid:29f4eb71-715c-48f4-b6ae-5e21ea40f5e2
Local pid:
pubs:93169
Source identifiers:
93169
Deposit date:
2012-12-19

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