Journal article

Sr(3)Co(2)O(4.33)h(0.84): an extended transition metal oxide-hydride.

Abstract:: Reaction of the n = 2 Ruddlesden-Popper oxide Sr(3)Co(2)O(5.80) with CaH(2) yields an extended oxide-hydride phase: Sr(3)Co(2)O(4.33)H(0.84). Neutron powder diffraction data reveal the material adopts a body-centered orthorhombic structure (Immm: a = 3.7551(5) Å, b = 3.7048(4) Å, c = 21.480(3) Å) in which the hydride ions are accommodated within disordered CoO(1.16)H(0.46) layers. Low temperature neutron powder diffraction data show no evidence for long-range magnetic order, suggesting the chemical disorder in the anion lattice of the material leads to magnetic frustration.

Publication status:: Published

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APA Style

Helps, R., Rees, N., & Hayward, M. (2010). Sr(3)Co(2)O(4.33)h(0.84): an extended transition metal oxide-hydride. Inorganic Chemistry, 49(23), 11062–11068.

MLA Style

Helps, R., et al. “Sr(3)Co(2)O(4.33)h(0.84): an Extended Transition Metal Oxide-Hydride.” Inorganic Chemistry, vol. 49, no. 23, 2010, pp. 11062–68.

Chicago Style

Helps, R, N Rees, and M Hayward. 2010. “Sr(3)Co(2)O(4.33)h(0.84): an Extended Transition Metal Oxide-Hydride.” Inorganic Chemistry 49 (23): 11062–68.
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Publisher copy:: 10.1021/ic101613b

Authors

+ Helps, R More by this author

Role:: Author

+ Rees, N More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Hayward, M More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: Inorganic chemistry More from this journal
Volume:: 49
Issue:: 23
Pages:: 11062-11068
Publication date:: 2010-12-01
DOI:: 10.1021/ic101613b
EISSN:: 1520-510X
ISSN:: 0020-1669

Language:: English
Pubs id:: pubs:93169
UUID:: uuid:29f4eb71-715c-48f4-b6ae-5e21ea40f5e2
Local pid:: pubs:93169
Source identifiers:: 93169
Deposit date:: 2012-12-19

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Copyright date:: 2010

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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