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LiO2: cryosynthesis and chemical/electrochemical reactivities

Abstract:

The reduction of O2 to solid Li2O2, via the intermediates O2- and LiO2, is the desired discharge reaction at the positive electrode of the aprotic Li-O2 batteries. In practice, a plethora of byproducts are identified together with Li2O2 and have been assigned to the side reactions between the reduced oxygen species (O2-, LiO2 and Li2O2) and the battery components (the cathode and electrolyte). Understanding the reactivity of these reduced oxygen species is critical for the development of stab...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1021/acs.jpclett.7b00680

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Publisher:
American Chemical Society Publisher's website
Journal:
Journal of Physical Chemistry Letters Journal website
Volume:
8
Issue:
10
Pages:
2334–2338
Publication date:
2017-05-08
Acceptance date:
2017-05-08
DOI:
ISSN:
1948-7185
Pubs id:
pubs:693920
URN:
uri:293015a1-44af-4a55-9efe-a5c825e9c0b8
UUID:
uuid:293015a1-44af-4a55-9efe-a5c825e9c0b8
Local pid:
pubs:693920

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