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Investigating the effect of macrocycle size in anion templated imidazolium-based interpenetrated and interlocked assemblies.

Abstract:

The effect of varying the size of the macrocycle component on the formation of anion templated imidazolium interpenetrated assemblies is investigated. Two different approaches to reducing the macrocycle size are undertaken and the stabilities of the resulting pseudorotaxanes incorporating substituted imidazolium threading components studied using (1)H NMR spectroscopy. Novel imidazolium axle containing interlocked rotaxane host structures are synthesised using chloride anion templated amide c...

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Publication status:
Published

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Publisher copy:
10.1039/c2ob26237a

Authors


Spence, GT More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Organic and biomolecular chemistry
Volume:
10
Issue:
36
Pages:
7282-7291
Publication date:
2012-09-05
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
URN:
uuid:2915ac1c-8779-4f79-adc9-a2b793bffb57
Source identifiers:
345607
Local pid:
pubs:345607

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