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Mono- and bi-nuclear titanium imido complexes supported by aryloxide ligands: fine control by ortho substituents

Abstract:

Reaction of the titanium imido complexes [Ti(NR)Cl2(py)3] (R = But, C6H3Me2-2,6 or C6H3Pri2-2,6; py = pyridine) with 2 equivalents of lithium aryloxide Li[OC6H3R′2-2,6] (R′ = Me, Pri or But) afforded the mononuclear four-or five-co-ordinate or binuclear four-co-ordinate complexes [{Ti(NR)(OC6H3R′2-2,6) 2(py)n}m] (m = 1, n = 1 or 2; m = 2, n = 0) depending on the identity of R and R′. The crystal structures of [Ti2(μ-NBut)2(OC6H 3Me2-2,6)4] 1 and [Ti(NC6H3Me2-2,6)(OC6H 3Me2-2,6)2(py)2] have be...

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Publication status:
Published

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Publisher copy:
10.1039/a703309e

Authors


Collier, PE More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
17
Pages:
2911-2919
Publication date:
1997-09-07
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:268586c2-86ae-4860-8f60-df2c9742618e
Source identifiers:
51427
Local pid:
pubs:51427
Language:
English

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