- Abstract:
-
The brucite-like Ca2+/Al3+ layered double hydroxide (LDH), Ca2Al(OH)6·NO3·2H2O, was synthesized using the coprecipitation method. The dicarboxylate anion 1,4-benzenedicarboxylate can be selectively intercalated into the layered double hydroxide Ca2Al(OH)6·NO3·2H2O from an aqueous solution containing an equimolar mixture of the 1,2- and 1,4-benzenedicarboxylates. Time-resolved in situ energy-dispersive X-ray diffraction studies of the competitive intercalation reaction reveal that initially bo...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/cm0002057
-
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- Journal:
- CHEMISTRY OF MATERIALS
- Volume:
- 12
- Issue:
- 7
- Pages:
- 1990-1994
- Publication date:
- 2000-07-05
- DOI:
- EISSN:
-
1520-5002
- ISSN:
-
0897-4756
- URN:
-
uuid:25d5cc29-0b71-44e2-a10f-df708f9ffa61
- Source identifiers:
-
51100
- Local pid:
- pubs:51100
- Language:
- English
- Copyright date:
- 2000
Journal article
Efficient separation of terephthalate and phthalate anions by selective ion-exchange intercalation in the layered double hydroxide Ca2Al(OH)(6)center dot NO3 center dot 2H(2)O
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