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Studies on the biomimetic synthesis of the manzamine alkaloids

Abstract:
The biomimetic synthesis of the manzamine-related alkaloid keramaphidin B is described. The key intramolecular Diels-Alder reaction proposed in the Baldwin and Whitehead hypothesis is demonstrated. An investigation of the modified biomimetic hypothesis proposed by Marazano et al. is also reported. Finally, an alternative synthesis of keramaphidin B by Grubbs methathesis is presented.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author


Journal:
CHEMISTRY-A EUROPEAN JOURNAL More from this journal
Volume:
5
Issue:
11
Pages:
3154-3161
Publication date:
1999-11-01
DOI:
ISSN:
0947-6539


Language:
English
Keywords:
Pubs id:
pubs:117903
UUID:
uuid:257fab8c-9a21-45ec-95ad-9ad3e0d1957e
Local pid:
pubs:117903
Source identifiers:
117903
Deposit date:
2012-12-19
ARK identifier:

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