Journal article

The cyclic and linear sweep voltammetry of regular and random arrays of microdisc electrodes: Theory

Abstract:: Microdisc electrode arrays are popular tools in electroanalytical chemistry. In linear sweep and cyclic voltammetry experiments, for optimum performance the individual discs in the array must have a centre-to-centre separation large enough to avoid diffusion zone overlap (which is also known as "shielding"), but not too large as to result in a waste of surface area. Using a 2-dimensional simulation method, this work examines in detail the currently accepted guidelines on centre-to-centre separation and identifies the key factors involved in the voltammetry of both regular and random arrays of microdisc (and nanodisc) electrodes. © 2005 Elsevier B.V. All rights reserved.

Publication status:: Published

Actions

Email

Email this record

Send the bibliographic details of this record to your email address.

Your Email
Please enter the email address that the record information will be sent to.

-
Your message (optional)
Please add any additional information to be included within the email.
Share
Cite

Cite this record

APA Style

Davies, T., & Compton, R. (2005). The cyclic and linear sweep voltammetry of regular and random arrays of microdisc electrodes: Theory. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 585(1), 63–82.

MLA Style

Davies, T, and R Compton. “The Cyclic and Linear Sweep Voltammetry of Regular and Random Arrays of Microdisc Electrodes: Theory.” JOURNAL OF ELECTROANALYTICAL CHEMISTRY, vol. 585, no. 1, 2005, pp. 63–82.

Chicago Style

Davies, T, and R Compton. 2005. “The Cyclic and Linear Sweep Voltammetry of Regular and Random Arrays of Microdisc Electrodes: Theory.” JOURNAL OF ELECTROANALYTICAL CHEMISTRY 585 (1): 63–82.
Print

Access Document

Publisher copy:: 10.1016/j.jelechem.2005.07.022

Authors

+ Davies, T More by this author

Role:: Author

+ Compton, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Physical & Theoretical Chem
Role:: Author

Journal:: JOURNAL OF ELECTROANALYTICAL CHEMISTRY More from this journal
Volume:: 585
Issue:: 1
Pages:: 63-82
Publication date:: 2005-11-01
DOI:: 10.1016/j.jelechem.2005.07.022
ISSN:: 0022-0728

Language:: English
Keywords:: random array

microdisc

microelectrodes

regular array

microdisc array

diffusion domain
UUID:: uuid:24f2959f-da6c-404e-951f-961e50c91ad7
Local pid:: pubs:39707
Source identifiers:: 39707
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_24f2959fda6c404e951f961e50c91ad7

Terms of use

Copyright date:: 2005

Licence:: Terms and Conditions of Use for Oxford University Research Archive

Views and Downloads

About views and downloads

If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP