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Chemical control of the dimensionality of the octahedral network of solar absorbers from the CuI-AgI-BiI3 phase space by synthesis of 3D CuAgBiI5

Abstract:

A newly reported compound, CuAgBiI5, is synthesized as powder, crystals, and thin films. The structure consists of a 3D octahedral Ag+/Bi3+ network as in spinel, but occupancy of the tetrahedral interstitials by Cu+ differs from those in spinel. The 3D octahedral network of CuAgBiI5 allows us to identify a relationship between octahedral site occupancy (composition) and octahedral motif (structure) across the whole CuI–AgI–BiI3 phase field, giving the ability to chemically control structural ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.inorgchem.1c02773

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Physics
Sub department:
Condensed Matter Physics
Role:
Author
ORCID:
0000-0003-0329-2822
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Role:
Author
ORCID:
0000-0003-2044-6774
Publisher:
American Chemical Society
Journal:
Inorganic Chemistry More from this journal
Volume:
60
Issue:
23
Pages:
18154-18167
Place of publication:
United States
Publication date:
2021-11-09
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Pmid:
34751565
Language:
English
Keywords:
Pubs id:
1210267
Local pid:
pubs:1210267
Deposit date:
2021-12-03

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