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On the performance optimisation of Fe catalysts in the microwave - assisted H2 production by the dehydrogenation of hexadecane

Abstract:
Microwave - assisted catalysis has previously been shown to offer unique advantages in the rapid production of hydrogen from hydrocarbons fuels. In this work, we have prepared a series of supported catalysts with varying iron content and support materials, and evaluated the resulting H2 production from hexadecane, a key representative component of diesel fuel. These catalysts, under microwave activation, exhibit high selectivity for H2 over hydrocarbons in the effluent gas. Microwave-assisted Fe catalysts supported on SiC at low Fe loading levels (<10 wt.%) are found to be the most effective catalytic system for rapid and high-purity H2 production from hexadecane.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1016/j.cattod.2018.03.036

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
St Anne's College
Role:
Author
ORCID:
0000-0003-3183-1686
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Materials
Role:
Author


Publisher:
Elsevier
Journal:
Catalysis Today More from this journal
Volume:
317
Pages:
29-35
Publication date:
2018-03-19
Acceptance date:
2018-03-16
DOI:
ISSN:
0920-5861


Keywords:
Pubs id:
pubs:830548
UUID:
uuid:247da7c2-5297-453c-9dce-e2708e0bba18
Local pid:
pubs:830548
Source identifiers:
830548
Deposit date:
2018-03-21

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