Stereochemical Assignment of Substituted 2-Aminobicyclo[3.1.0]hexane and 2-Aminobicyclo[5.1.0]octane Derivatives via Single Crystal X-ray Diffraction

Christensen, K; Csatayova, K; Davies, S; Lee, J; Roberts, P; Thompson, A; Thomson, J

Journal article

Stereochemical Assignment of Substituted 2-Aminobicyclo[3.1.0]hexane and 2-Aminobicyclo[5.1.0]octane Derivatives via Single Crystal X-ray Diffraction

Abstract:: Crystals of benzyl (RS,RS,RS)-7-phenylbicyclo[5.1.0]octan-2-ylcarbamate 9 and (RS,RS,RS)-N-[3′-(4′-methylpiperazin-1′-yl)propyl]-N-{5- (4‴-cyanophenyl)bicyclo[3.1.0]hexan-2-yl}amine dihydrochloride 10•2HCl were synthesised and single crystal X-ray diffraction was used to establish unambiguously the relative configurations within these structures. Compound 9 crystallizes in the orthorhombic space group P2 1 2 1 2 1 with cell parameters of a = 6.85340(10) Å, b = 9.8732(2) Å, c = 27.5407(6) Å, V...
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APA Style

Christensen, K., Csatayova, K., Davies, S., Lee, J., Roberts, P., Thompson, A., & Thomson, J. (2011). Stereochemical Assignment of Substituted 2-Aminobicyclo[3.1.0]hexane and 2-Aminobicyclo[5.1.0]octane Derivatives via Single Crystal X-ray Diffraction. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 41(7), 1007–1012.

MLA Style

Christensen, K., et al. “Stereochemical Assignment of Substituted 2-Aminobicyclo[3.1.0]Hexane and 2-Aminobicyclo[5.1.0]Octane Derivatives via Single Crystal X-Ray Diffraction.” JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, vol. 41, no. 7, 2011, pp. 1007–12.

Chicago Style

Christensen, K, K Csatayova, S Davies, J Lee, P Roberts, A Thompson, and J Thomson. 2011. “Stereochemical Assignment of Substituted 2-Aminobicyclo[3.1.0]Hexane and 2-Aminobicyclo[5.1.0]Octane Derivatives via Single Crystal X-Ray Diffraction.” JOURNAL OF CHEMICAL CRYSTALLOGRAPHY 41 (7): 1007–12.
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Publisher copy:: 10.1007/s10870-011-0034-6

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+ Christensen, K More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Inorganic Chemistry

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Author

+ Csatayova, K More by this author

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Author

+ Davies, S More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Organic Chemistry

Role:

Author

+ Lee, J More by this author

Role:

Author

+ Roberts, P More by this author

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Author

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Bibliographic Details

Journal:: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
Volume:: 41
Issue:: 7
Pages:: 1007-1012
Publication date:: 2011-07-01
DOI:: 10.1007/s10870-011-0034-6
EISSN:: 1572-8854
ISSN:: 1074-1542

Item Description

Language:: English
Keywords:: cis-SCH-A

Simmons-Smith

Allylic carbamate

Cyclopropane

X-ray crystal structure
Pubs id:: pubs:162210
UUID:: uuid:23e36f46-9d71-4e95-9f00-8f28e6d0e5e3
Local pid:: pubs:162210
Source identifiers:: 162210
Deposit date:: 2012-12-19

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Journal article

Stereochemical Assignment of Substituted 2-Aminobicyclo[3.1.0]hexane and 2-Aminobicyclo[5.1.0]octane Derivatives via Single Crystal X-ray Diffraction

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