- Abstract:
- We have validated a novel detagging strategy featuring the unmasking of a fluorous-tagged silane to a hydroxy moiety. The fluorous silylated bicyclononane, prepared from the titanium-mediated annulation of 1-acetylcyclohexene and a fluorous-tagged allylsilane, was successfully detagged under Fleming-type oxidation conditions. The stereochemistry of the resulting hydroxylated product indicates retention of configuration upon detagging in line with the non-fluorous variant of this transformation. © 2009.
- Publication status:
- Published
- Publisher copy:
- 10.1016/j.jfluchem.2009.05.017
-
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- Volume:
- 130
- Issue:
- 12
- Pages:
- 1151-1156
- Publication date:
- 2009-12-05
- DOI:
- ISSN:
-
0022-1139
- URN:
-
uuid:239c5377-b9ff-45d6-ac59-3711e71cc421
- Source identifiers:
-
45956
- Local pid:
- pubs:45956
- Keywords:
- Copyright date:
- 2009
Conference
Oxidative detagging of fluorous organosilanes
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