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Relative orientation between the beta-ionone ring and the polyene chain for the chromophore of rhodopsin in native membranes.

Abstract:

Rotational resonance solid state nuclear magnetic resonance has been used to determine the relative orientation of the beta-ionone ring and the polyene chain of the chromophore 11-Z-retinylidene of rhodopsin in rod outer segment membranes from bovine retina. The bleached protein was regenerated with either 11-Z-[8,18-(13)C(2)]retinal or 11-Z-[8,16/17(13)C(2)]retinal, the latter having only one (13)C label at either of the chemically equivalent positions 16 and 17. Observation of (13)C selecti...

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Publication status:
Published

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Publisher copy:
10.1021/bi020007o

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Journal:
Biochemistry More from this journal
Volume:
41
Issue:
24
Pages:
7549-7555
Publication date:
2002-06-01
DOI:
EISSN:
1520-4995
ISSN:
0006-2960
Language:
English
Keywords:
Pubs id:
pubs:100093
UUID:
uuid:22f19c72-09e4-48df-9d04-8e857e158d14
Local pid:
pubs:100093
Source identifiers:
100093
Deposit date:
2012-12-19

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