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Carbon monoxide activation by a molecular aluminium imide: C-O bond cleavage and C-C bond formation

Abstract:

Anionic molecular imide complexes of aluminium are accessible via a rational synthetic approach involving the reactions of organo azides with a potassium aluminyl reagent. In the case of K2 [(NON)Al(NDipp)]2 (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethyl-xanthene; Dipp=2,6-diisopropylphenyl) structural characterization by X-ray crystallography reveals a short Al-N distance, which is thought primarily to be due to the low coordinate nature of the nitrogen centre. The Al-N ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/anie.201916073

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More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Role:
Author
ORCID:
0000-0002-7311-1663
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Role:
Author
ORCID:
0000-0001-9998-9434
Publisher:
Wiley Publisher's website
Journal:
Angewandte Chemie International Edition Journal website
Volume:
59
Issue:
12
Pages:
4897-4901
Publication date:
2020-02-18
Acceptance date:
2020-01-30
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Pmid:
31999037
Pubs id:
1086809
Local pid:
pubs:1086809
Language:
English
Keywords:
Format:
Print-Electronic

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