- Abstract:
-
Anionic molecular imide complexes of aluminium are accessible via a rational synthetic approach involving the reactions of organo azides with a potassium aluminyl reagent. In the case of K2 [(NON)Al(NDipp)]2 (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethyl-xanthene; Dipp=2,6-diisopropylphenyl) structural characterization by X-ray crystallography reveals a short Al-N distance, which is thought primarily to be due to the low coordinate nature of the nitrogen centre. The Al-N ...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Publisher:
- Wiley Publisher's website
- Journal:
- Angewandte Chemie International Edition Journal website
- Volume:
- 59
- Issue:
- 12
- Pages:
- 4897-4901
- Publication date:
- 2020-02-18
- Acceptance date:
- 2020-01-30
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Pmid:
-
31999037
- Pubs id:
-
1086809
- Local pid:
- pubs:1086809
- Language:
- English
- Keywords:
- Format:
- Print-Electronic
- Copyright holder:
- Wiley
- Copyright date:
- 2020
- Rights statement:
- © 2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
- Notes:
- This is the accepted manuscript version of the article. The final version is available from Wiley at: https://doi.org/10.1002/anie.201916073
Journal article
Carbon monoxide activation by a molecular aluminium imide: C-O bond cleavage and C-C bond formation
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