Journal article

Terminal Aziridines by Addition of Grignard Reagents or Organoceriums to an (alpha-Chloro)sulfinylimine

Abstract:: Reaction of N-(2-chloroethylidene)-tert-butylsulfinamide with Grignard reagents or organoceriums gives terminal N-tert-butylsulfinyl aziridines in good yields and (mainly with organoceriums) good diastereomeric ratios. Oxidation of terminal N-tert-butylsulfinyl aziridines provides synthetically useful terminal N-Bus (Bus = tert-butylsulfonyl) aziridines. © Georg Thieme Verlag Stuttgart.

Publication status:: Published

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APA Style

Hodgson, D., Kloesges, J., & Evans, B. (2009). Terminal Aziridines by Addition of Grignard Reagents or Organoceriums to an (alpha-Chloro)sulfinylimine. SYNTHESIS-STUTTGART, 2009(11), 1923–1932.

MLA Style

Hodgson, D., et al. “Terminal Aziridines by Addition of Grignard Reagents or Organoceriums to an (Alpha-Chloro)Sulfinylimine.” SYNTHESIS-STUTTGART, vol. 2009, no. 11, 2009, pp. 1923–32.

Chicago Style

Hodgson, D, J Kloesges, and B Evans. 2009. “Terminal Aziridines by Addition of Grignard Reagents or Organoceriums to an (Alpha-Chloro)Sulfinylimine.” SYNTHESIS-STUTTGART 2009 (11): 1923–32.
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Publisher copy:: 10.1055/s-0029-1216799

Authors

+ Hodgson, D More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Organic Chemistry
Role:: Author

+ Kloesges, J More by this author

Role:: Author

+ Evans, B More by this author

Role:: Author

Journal:: SYNTHESIS-STUTTGART More from this journal
Volume:: 2009
Issue:: 11
Pages:: 1923-1932
Publication date:: 2009-06-03
DOI:: 10.1055/s-0029-1216799
EISSN:: 1437-210X
ISSN:: 0039-7881

Language:: English
Keywords:: chiral auxiliaries

nucleophilic addition

aziridines

organoceriums

imines
Pubs id:: pubs:41242
UUID:: uuid:228e4f71-0595-466c-bd35-e086adab3865
Local pid:: pubs:41242
Source identifiers:: 41242
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2009

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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