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Thesis

Borane, boryl and borylene complexes of electron rich metal centres

Abstract:

The synthesis and characterisation of a series of novel borane, boryl and borylene complexes of electron rich group 8 and 9 metal centres are described in this thesis.

Chapter 3 reports on the properties of a highly nucleophile tolerant borylene system, [CpFe(dmpe)(BNMe₂)]⁺, together with its surprising formation via an unprecedented spontaneous halide ejection process. The incorporation of strongly electron releasing ancillary phosphine ligands is reflected by an Fe-B distance (ca. ...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Research group:
Aldridge Group
Oxford college:
Queen's College
Role:
Author
More by this author
Division:
MPLS
Department:
Chemistry
Role:
Author

Contributors

Division:
MPLS
Department:
Chemistry
Role:
Supervisor

Publication date:
2012
DOI:
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
Oxford University, UK

Language:
English
Keywords:
Subjects:
UUID:
uuid:211632be-dd28-439c-9dee-0a214a7dc660
Local pid:
ora:6152
Deposit date:
2012-03-29

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