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Sonoelectrochemistry in highly resistive media: Mass transport effects

Abstract:

Sonovoltammetry methodology is studied for the enhancement of electrochemical processes in highly resistive media. As model systems the reduction of [FeCp*2]PF6 (with Cp℧ = η5-C5Me5) and the oxidation of FeCp*2 in acetonitrile are examined at a 25 μm diameter Pt microdisk electrode. Both in the presence and in the absence of supporting electrolyte ultrasound induces a strong increase in the observed limiting current in agreement with an increase in mass transport or, associated with this, a c...

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
ELECTROANALYSIS
Volume:
10
Issue:
8
Pages:
562-566
Publication date:
1998-07-01
DOI:
ISSN:
1040-0397
Source identifiers:
36676
Language:
English
Keywords:
UUID:
uuid:20ed8f17-7a55-434c-beec-630b30842c6c
Local pid:
pubs:36676
Deposit date:
2012-12-19

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