Journal article

Percolation-induced ferrimagnetism from vacancy order in [Gua]Mn1–xFe2x/3(HCOO)3 hybrid perovskites

Abstract:: We report the magnetic behavior of the hybrid perovskites [Gua]Mn1–xFe2x/3□x/3(HCOO)3 (0 ≤ x ≤ 0.88), showing that vacancy ordering drives bulk ferrimagnetism for x > 0.6. The behavior is rationalized in terms of a simple microscopic model of percolation-induced ferrimagnetism. Monte Carlo simulations driven by this model reproduce the experimental dependence of magnetic susceptibility on x and show that, at intermediate compositions, domains of short-range vacancy order lead to the emergence of local magnetization. Our results open up a new avenue for the design of multiferroic hybrid perovskites.

Publication status:: Published

Peer review status:: Peer reviewed

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APA Style

Bulled, J. M., Willis, A., Faure Beaulieu, Z., Cassidy, S. J., Bruckmoser, J., Boström, H. L. B., & Goodwin, A. L. (2024). Percolation-induced ferrimagnetism from vacancy order in [Gua]Mn1–xFe2x/3(HCOO)3 hybrid perovskites. Journal of the American Chemical Society, 146(20), 13714–13718.

MLA Style

Bulled, JM, et al. “Percolation-Induced Ferrimagnetism from Vacancy Order in [Gua]Mn1–xFe2x/3(HCOO)3 Hybrid Perovskites.” Journal of the American Chemical Society, vol. 146, no. 20, 2024, pp. 13714–18.

Chicago Style

Bulled, JM, A Willis, Z Faure Beaulieu, et al. 2024. “Percolation-Induced Ferrimagnetism from Vacancy Order in [Gua]Mn1–xFe2x/3(HCOO)3 Hybrid Perovskites.” Journal of the American Chemical Society 146 (20): 13714–18.
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Publisher copy:: 10.1021/jacs.4c03407

Authors

+ Bulled, JM More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author
ORCID:: 0000-0001-5017-0313

+ Willis, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author
ORCID:: 0000-0002-2317-8958

+ Faure Beaulieu, Z More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Cassidy, SJ More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Oxford college:: St Hilda's College
Role:: Author
ORCID:: 0000-0002-4297-1425

+ Bruckmoser, J More by this author

Role:: Author

More authors...

+ Leverhulme Trust More from this funder

Grant:: RPG-2018-268

+ European Research Council More from this funder

Grant:: 788144

Publisher:: American Chemical Society
Journal:: Journal of the American Chemical Society More from this journal
Volume:: 146
Issue:: 20
Pages:: 13714-13718
Place of publication:: United States
Publication date:: 2024-05-09
Acceptance date:: 2024-04-30
DOI:: 10.1021/jacs.4c03407
EISSN:: 1520-5126
ISSN:: 0002-7863
Pmid:: 38723156

Language:: English
Pubs id:: 1996096
Local pid:: pubs:1996096
Deposit date:: 2024-05-21
ARK identifier:: ark:/29072/ora_1fab83357c314f8a9ce6dfe39eea5344

Terms of use

Copyright holder:: Bulled et al.
Copyright date:: 2024
Rights statement:: © 2024 The Authors. Published by American Chemical Society. This article is licensed under CC-BY 4.0.

Licence:: CC Attribution (CC BY)

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