Journal article

Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]

Abstract:: The solubility of manganese in mercury was determined electrochemically via amalgamation and stripping in the room temperature ionic liquid n-hexyltriethylammonium bis(trifluoromethanesulfonyl)imide, [N 6,2,2,2][NTf2]. A hemispherical mercury electrode was made by electrodepositing mercury onto a planar platinum microelectrode. Cyclic voltammetry of Mn2+ in [N6,2,2,2][NTf2] at the mercury microhemisphere electrode was investigated at temperatures of 298, 303 and 313 K. The solubility of Mn in Hg was determined on the basis of the charge under the reduction peak (Mn2+ → Mn0) and the corresponding reoxidation. © 2008 WILEY-VCH Verlag.

Publication status:: Published

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APA Style

Rogers, E., Sljukic, B., Hardacre, C., & Compton, R. (2008). Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(trifluoromethanesulfonyl)imide, [N-6,N-2,N-2,N-2][NTf2]. ELECTROANALYSIS, 20(24), 2603–2607.

MLA Style

Rogers, E., et al. “Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(Trifluoromethanesulfonyl)Imide, [N-6,N-2,N-2,N-2][NTf2].” ELECTROANALYSIS, vol. 20, no. 24, 2008, pp. 2603–07.

Chicago Style

Rogers, E, B Sljukic, C Hardacre, and R Compton. 2008. “Electrochemical Determination of Manganese Solubility in Mercury via Amalgamation and Stripping in the Room Temperature Ionic Liquid n-Hexyltriethylammonium Bis(Trifluoromethanesulfonyl)Imide, [N-6,N-2,N-2,N-2][NTf2].” ELECTROANALYSIS 20 (24): 2603–7.
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Publisher copy:: 10.1002/elan.200804393

Authors

+ Rogers, E More by this author

Role:: Author

+ Sljukic, B More by this author

Role:: Author

+ Hardacre, C More by this author

Role:: Author

+ Compton, R More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Physical & Theoretical Chem
Role:: Author

Journal:: ELECTROANALYSIS More from this journal
Volume:: 20
Issue:: 24
Pages:: 2603-2607
Publication date:: 2008-12-01
DOI:: 10.1002/elan.200804393
EISSN:: 1521-4109
ISSN:: 1040-0397

Language:: English
Keywords:: Mercury microhemisphere electrode

Managanese Solubility in mercury

Room temperature ionic liquids

Manganese(II) reduction
UUID:: uuid:1e6cbf6f-814d-41ed-9a04-cf44464e938b
Local pid:: pubs:41017
Source identifiers:: 41017
Deposit date:: 2012-12-19

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Copyright date:: 2008

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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