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Synthesis and Structure of Two New Strontium Germanium Nitrides: Sr(3)Ge(2)N(2) and Sr(2)GeN(2).

Abstract:

We report the structures of two new strontium germanium nitrides synthesized as crystals from the elements in sealed Nb tubes at 750 degrees C using liquid Na as a growth medium. Sr(3)Ge(2)N(2) is isostructural with the previously reported Ba analogue. It crystallizes in P2(1)/m (No. 11), with a = 9.032(2) Å, b = 3.883(1) Å, c = 9.648(2) Å and beta = 112.42(3) degrees, and has two formula units per unit cell. It contains GeN(2)(4)(-) units and additionally |Ge(2)(-) zigzag chains. Sr(2)GeN(2)...

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Publication status:
Published

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Publisher copy:
10.1021/ic960518x

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
35
Issue:
24
Pages:
7009-7012
Publication date:
1996-11-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:1d2585fd-61a6-4b26-a808-cc909d0b5d26
Source identifiers:
46242
Local pid:
pubs:46242
Language:
English

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