- Abstract:
-
The manipulation of distortions in perovskite structures is critical to tailoring the properties of these materials for a variety of applications. Here we demonstrate a violation of traditional tilt rules in the double perovskite analogue (NH4)2SrFe(CN)6•2H2O. The forbidden tilt pattern we observe arises through coupling to hydration-driven Jahn-Teller-like distortions of the Sr coordination environment. Access to novel distortion mechanisms and the ability to switch these distortions on and ...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Accepted Manuscript
- Files:
-
-
(pdf, 544.1kb)
-
- Publisher copy:
- 10.1021/jacs.6b06785
-
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- Funding agency for:
- Hill, JA
- Funding agency for:
- Goodwin, A
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 138
- Issue:
- 35
- Pages:
- 11121–11123
- Publication date:
- 2016-08-17
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- Pubs id:
-
pubs:640912
- URN:
-
uri:1d03f27f-f025-4cbb-9532-06a3864b676b
- UUID:
-
uuid:1d03f27f-f025-4cbb-9532-06a3864b676b
- Local pid:
- pubs:640912
- Paper number:
- 35
- Language:
- English
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
-
Copyright © 2016 American Chemical Society. This is the accepted manuscript version of the article. The final version is available online from the American Chemical Society at: https://doi.org/10.1021/jacs.6b06785
Journal article
Guest-activated forbidden tilts in a molecular perovskite analogue
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