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Guest-activated forbidden tilts in a molecular perovskite analogue

Abstract:

The manipulation of distortions in perovskite structures is critical to tailoring the properties of these materials for a variety of applications. Here we demonstrate a violation of traditional tilt rules in the double perovskite analogue (NH4)2SrFe(CN)6•2H2O. The forbidden tilt pattern we observe arises through coupling to hydration-driven Jahn-Teller-like distortions of the Sr coordination environment. Access to novel distortion mechanisms and the ability to switch these distortions on and ...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/jacs.6b06785

Authors


Duyker, SG More by this author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Howard, CJ More by this author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
138
Issue:
35
Pages:
11121–11123
Publication date:
2016-08-17
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Pubs id:
pubs:640912
URN:
uri:1d03f27f-f025-4cbb-9532-06a3864b676b
UUID:
uuid:1d03f27f-f025-4cbb-9532-06a3864b676b
Local pid:
pubs:640912
Paper number:
35
Language:
English

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