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Multiparameter estimation in voltammetry when an electron transfer process is coupled to a chemical reaction

Abstract:

Estimation of thermodynamic and kinetic parameters in electrochemical studies is usually undertaken via comparison of the experimental results with theory based on a model that mimics the experiment. The present study examines the credibility of transient d.c. and a.c. voltammetric theory-experiment comparisons for recovery of the parameters needed to model the ubiquitous mechanism when an electron transfer (E) reaction is followed by a chemical (C) step in the EC process ([Formula: see text]...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1021/acs.analchem.5b04820

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Institution:
University of Oxford
Department:
Oxford, MPLS, Mathematical Institute
Role:
Author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Mathematical Institute
Role:
Author
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Australian Research Council More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Analytical Chemistry Journal website
Volume:
88
Issue:
9
Pages:
4724-4732
Publication date:
2016-04-04
DOI:
EISSN:
1520-6882
ISSN:
0003-2700
URN:
uuid:1cb488d8-dd42-42ec-9dcc-7893d21e6dfa
Source identifiers:
614035
Local pid:
pubs:614035
Paper number:
9
Language:
English

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