Journal article
Multiparameter estimation in voltammetry when an electron transfer process is coupled to a chemical reaction
- Abstract:
-
Estimation of thermodynamic and kinetic parameters in electrochemical studies is usually undertaken via comparison of the experimental results with theory based on a model that mimics the experiment. The present study examines the credibility of transient d.c. and a.c. voltammetric theory-experiment comparisons for recovery of the parameters needed to model the ubiquitous mechanism when an electron transfer (E) reaction is followed by a chemical (C) step in the EC process ([Formula: see text]...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
-
(Accepted manuscript, pdf, 545.8KB)
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(Accepted manuscript, pdf, 1.5MB)
-
- Publisher copy:
- 10.1021/acs.analchem.5b04820
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Authors
Funding
Australian Research Council
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Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Analytical Chemistry Journal website
- Volume:
- 88
- Issue:
- 9
- Pages:
- 4724-4732
- Publication date:
- 2016-04-04
- Acceptance date:
- 2016-04-04
- DOI:
- EISSN:
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1520-6882
- ISSN:
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0003-2700
- Source identifiers:
-
614035
Item Description
- Language:
- English
- Pubs id:
-
pubs:614035
- UUID:
-
uuid:1cb488d8-dd42-42ec-9dcc-7893d21e6dfa
- Local pid:
- pubs:614035
- Deposit date:
- 2016-05-11
Terms of use
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2016
- Notes:
- Copyright © 2016 American Chemical Society. This is the accepted manuscript version of the article. The final version is available online from the American Chemical Society at: [10.1021/acs.analchem.5b04820]
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