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Dynamics of ion transfer potentials at liquid-liquid interfaces: the case of multiple species.

Abstract:

The dynamic evolution of a water-nitrobenzene system with both solvents containing an initially equimolar mixture of two monovalent binary electrolytes, sharing a common cation, is simulated using the Nernst-Planck-Poisson finite difference method. The effect of single ion partition coefficients and diffusion coefficients on the evolution of potential across the liquid-liquid interface is investigated. Two separable components of the potential difference are observed: a static component local...

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Publication status:
Published

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Publisher copy:
10.1021/jp204826y

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
journal of physical chemistry. B More from this journal
Volume:
115
Issue:
43
Pages:
12429-12440
Publication date:
2011-11-01
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Language:
English
UUID:
uuid:1c2e5514-5362-4bfb-a799-26318a3685c3
Local pid:
pubs:180429
Source identifiers:
180429
Deposit date:
2012-12-19

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