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REDOX-ACTIVE LITHIUM-SELECTIVE IONOPHORES BASED ON NEW 2,9-BIS(FERROCENYL) SUBSTITUTED PHENANTHROLINE DERIVATIVES

Abstract:

A variety of new redox-active 2,9-bis(ferrocenyl)-substituted phenanthroline derivatives have been prepared, and the structure of one of them, 2,9-bis(ferrocenyl)ethenyl-1,10-phenanthroline, has been determined by an X-ray diffraction study. Solution 1H NMR complexation studies suggest the 2,9-bis(ferrocenyl)vinylic- and amine-linked phenanthroline ligands form complexes with the ligand and Li+ in 2 : 1 stoichiometric ratio, whereas Schiff-base-containing ionophores produced an equilibrium mi...

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Publication status:
Published

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Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
476
Issue:
1
Pages:
63-72
Publication date:
1994-08-09
DOI:
ISSN:
0022-328X
URN:
uuid:1bd70339-1916-4d0e-be38-6b3b3da4ee56
Source identifiers:
44601
Local pid:
pubs:44601

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