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Template-directed synthesis of linear porphyrin oligomers: classical, Vernier and mutual Vernier

Abstract:

Three different types of template-directed syntheses of linear porphyrin oligomers are presented. In the classical approach the product has the same number of binding sites as the template, whereas in Vernier reactions the product has the lowest common multiple of the numbers of binding sites in the template and the building block. Mutual Vernier templating is like Vernier templating except that both strands of the Vernier complex undergo coupling simultaneously, so that it becomes impossible...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1039/c6sc05355f

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Engineering and Physical Sciences Research Council More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Science Journal website
Volume:
8
Issue:
4
Pages:
2729-2740
Publication date:
2017-01-20
Acceptance date:
2017-01-20
DOI:
EISSN:
2041-6539
ISSN:
2041-6520
Pubs id:
pubs:689270
URN:
uri:1bc7f38f-065c-448a-aee7-6cf4161f24f9
UUID:
uuid:1bc7f38f-065c-448a-aee7-6cf4161f24f9
Local pid:
pubs:689270
Language:
English
Keywords:

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