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Vertex-linked ZnO2S2 tetrahedra in the oxysulfide BaZnOS: a new coordination environment for zinc in a condensed solid.

Abstract:

The wide-band-gap semiconductor BaZnOS adopts a high-symmetry modification of the SrZnO2 structure type and contains layers of vertex-linked ZnO2S2 tetrahedra, which represent a novel coordination environment for zinc in the solid state. BaZnOS: orthorhombic, space group Cmcm; a = 3.9619(2) angstroms, b = 12.8541(7) angstroms, c = 6.1175(4) angstroms, Z = 4. Diffuse-reflectance spectroscopy measurements reveal a direct band gap of 3.9(3) eV, consistent with the white color and the results of ...

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Publication status:
Published

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Publisher copy:
10.1021/ic051240o

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
44
Issue:
24
Pages:
9092-9096
Publication date:
2005-11-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:1bc02d7d-7a7d-4f08-a212-ad26636e12d5
Source identifiers:
33313
Local pid:
pubs:33313
Language:
English

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