- Abstract:
-
The wide-band-gap semiconductor BaZnOS adopts a high-symmetry modification of the SrZnO2 structure type and contains layers of vertex-linked ZnO2S2 tetrahedra, which represent a novel coordination environment for zinc in the solid state. BaZnOS: orthorhombic, space group Cmcm; a = 3.9619(2) angstroms, b = 12.8541(7) angstroms, c = 6.1175(4) angstroms, Z = 4. Diffuse-reflectance spectroscopy measurements reveal a direct band gap of 3.9(3) eV, consistent with the white color and the results of ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic051240o
-
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- Journal:
- Inorganic chemistry
- Volume:
- 44
- Issue:
- 24
- Pages:
- 9092-9096
- Publication date:
- 2005-11-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:1bc02d7d-7a7d-4f08-a212-ad26636e12d5
- Source identifiers:
-
33313
- Local pid:
- pubs:33313
- Language:
- English
- Copyright date:
- 2005
Journal article
Vertex-linked ZnO2S2 tetrahedra in the oxysulfide BaZnOS: a new coordination environment for zinc in a condensed solid.
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