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Journal article

THE RING EXPANSION OF PENAMS TO CEPHAMS - A POSSIBLE BIOMIMETIC PROCESS

Abstract:
Reaction of a 2β-bromomethyl penam with triphenyltin hydride gave, via ring expansion of the derived 2β-methyl radical, the corresponding cepham system; a similar process may be in operation during the biosynthetic ring expansion of penicillin N to deacetoxycephalasporin C.1. © 1988.
Publication status:
Published

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Journal:
TETRAHEDRON More from this journal
Volume:
44
Issue:
18
Pages:
5953-5957
Publication date:
1988-01-01
DOI:
ISSN:
0040-4020
Language:
English
Pubs id:
pubs:42986
UUID:
uuid:1ba8f00c-d986-4cc6-9d5b-294449b911fd
Local pid:
pubs:42986
Source identifiers:
42986
Deposit date:
2012-12-19

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