Journal article
THE RING EXPANSION OF PENAMS TO CEPHAMS - A POSSIBLE BIOMIMETIC PROCESS
- Abstract:
- Reaction of a 2β-bromomethyl penam with triphenyltin hydride gave, via ring expansion of the derived 2β-methyl radical, the corresponding cepham system; a similar process may be in operation during the biosynthetic ring expansion of penicillin N to deacetoxycephalasporin C.1. © 1988.
- Publication status:
- Published
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- Publisher copy:
- 10.1016/S0040-4020(01)81453-8
Authors
- Journal:
- TETRAHEDRON More from this journal
- Volume:
- 44
- Issue:
- 18
- Pages:
- 5953-5957
- Publication date:
- 1988-01-01
- DOI:
- ISSN:
-
0040-4020
- Language:
-
English
- Pubs id:
-
pubs:42986
- UUID:
-
uuid:1ba8f00c-d986-4cc6-9d5b-294449b911fd
- Local pid:
-
pubs:42986
- Source identifiers:
-
42986
- Deposit date:
-
2012-12-19
- ARK identifier:
Terms of use
- Copyright date:
- 1988
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