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A germanate built from a 6(8)12(6) cavity cotemplated by an (H2O)16 cluster and 2-methylpiperazine.

Abstract:
Totally tubular: A new tubular germanate is cotemplated by 2-methylpiperazine and an (H2O)16 cluster in a hydro(solvo)-thermal synthesis. The germanate features a large, highly symmetric 68126 cavity (see picture; yellow sphere) built from 12 Ge7X19 (X = O, OH, F) clusters (GeX6 red, GeX5 yellow, GeX4 green). (Figure Presented). © 2008 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200801375

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
Angewandte Chemie (International ed. in English)
Volume:
47
Issue:
41
Pages:
7868-7871
Publication date:
2008-01-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Source identifiers:
321985
Language:
English
Keywords:
Pubs id:
pubs:321985
UUID:
uuid:1b92ee59-7b63-4dfe-b215-87e535d02383
Local pid:
pubs:321985
Deposit date:
2012-12-19

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