A germanate built from a 6(8)12(6) cavity cotemplated by an (H2O)16 cluster and 2-methylpiperazine.
- Totally tubular: A new tubular germanate is cotemplated by 2-methylpiperazine and an (H2O)16 cluster in a hydro(solvo)-thermal synthesis. The germanate features a large, highly symmetric 68126 cavity (see picture; yellow sphere) built from 12 Ge7X19 (X = O, OH, F) clusters (GeX6 red, GeX5 yellow, GeX4 green). (Figure Presented). © 2008 Wiley-VCH Verlag GmbH and Co. KGaA.
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